Acid recovery
With expert knowledge in metal treatment, Ovivo offers an innovative process for acid recovery of the passivation process, which can be returned to an anodizing bath in the form of acidic electrolyte. For example, during the aluminium anodizing process, sulphuric acidic electrolyte is enriched with aluminium ions. It is not uncommon to partly dispose the acid when Al concentration is too high. Ovivo’s Goemapur™ Al acid recovery system enables acidic electrolyte recovery, saving chemicals, wastewater and energy.
Anodizing, or anodising, is an electrolytic passivation process which is used in order to increase the thickness of the natural oxide layer on the surface of aluminium parts. During this process aluminium parts are the anode electrode of an electrical circuit. Anodizing parts leads to increased corrosion resistance and provides better adhesion for paint primers and glues.
Sulfuric acid is the most widely used solution to produce anodized coating. Used for aluminum railing system, profiles, aluminum alloy panels, extruded aluminum trusses, coils, aircraft wings, roof railing for cars, window and door fittings....
During aluminium anodizing processes, the sulphuric acidic electrolyte bath is enriched with aluminium. On average, between 7 and 10 g Al/m² of the surface to be anodized dissolves (1.5 Amps/dm2, 45 minutes anodizing time). When the aluminium content exceeds 20g/l the electrolyte cannot normally be used. Goemapur Al acid recovery system ensures constant aluminium concentrations without the need for dumping, offering considerable savings not only in terms of chemicals but also in terms of energy.
With the fully automatic Goemapur Al unit, there is no need for manual draining, dumping and neutralizing.
The anodizing bath solution is pumped into a buffer tank before being treated in a batch process with a column ion exchanger, producing waste aluminium sulphate and returning acidic electrolyte to the bath. The process repeats until the plant is turned off manually.
Using conventional methods (without the Goemapur Al design), the anodizing bath is partially drained, the waste neutralized and the bath refilled with new electrolyte. This ensures that the concentration of aluminium remains between 10 and 15 g/l, but incurs chemical costs for acidic waste neutralization (for which caustic soda is required) and electrolyte refill (topping up the bath with sulphuric acid). If the aluminium concentration remains constant,considerable chemical savings may be made.
As the concentration of aluminium in the acid electrolyte bath increases, so too does resistance. Current density falls since the anodizing process (itself a function of current) becomes less efficient. To keep the current density constant, voltage must also be increased as aluminium concentrations rise. This increases energy consumption. If the aluminium concentration remains constant, significant savings can also be made in terms of energy consumption.
Using a Goemapur Al unit, the volume and strength of acidic waste is considerably reduced, as is the need to neutralize waste electrolyte using expensive chemical supplements (caustic soda). Using the Goemapur Al process, a small quantity of weak acidic aluminium sulphate is produced near continuously, rather than the occasional, much larger volumes of more strongly acidic spent electrolyte. Waste products for the Goemapur Al process are simpler and cheaper to dispose of; this may be a particularly important consideration for those who do not have their own wastewater treatment plant on site.
Even aluminium oxide layers result from a constant current-voltage relation, offering an additional guarantee of quality.